Chlorido-(η6-p-cymene)-(bis(pyrazol-1-yl)methane- κ2N,Nl)Osmium(II) Tetrafluoroborate, C17H22BClF4N4Os
dc.contributor.author | Mambanda, A. | |
dc.contributor.author | Kanyora, A. K. | |
dc.contributor.author | Ongoma, P. | |
dc.contributor.author | Gichumbi, J. | |
dc.contributor.author | Omondi, R. O. | |
dc.date.accessioned | 2025-02-21T09:11:04Z | |
dc.date.available | 2025-02-21T09:11:04Z | |
dc.date.issued | 2022 | |
dc.description | Research Article | |
dc.description.abstract | The powder of the arene osmium(II) complex, [Os(II)(dpzm)(η6-p-cym)Cl]BF4 (dpzm = di(1H-pyrazol-1-yl)methane; η6-p-cym = para-cymene), with a formula of C17H22BClF4N4Os (referred to herein as 1) was isolated from the reaction of [(η6-p-cym)Os(µ-Cl)(Cl)]2 with dpzm dissolved in acetonitrile and under a flow of nitrogen gas. It was characterized by spectroscopic techniques (viz., FTIR, 1H NMR, UV-Visible absorption). Yellow crystal blocks of 1 were grown by the slow evaporation from the methanolic solution of its powder. The single-crystal X-ray structure of 1 was solved by diffraction analysis on a Bruker APEX Duo CCD area detector diffractometer using the Cu(Kα), 2 = 1.54178 Å as the radiation source, and 1 crystallizes in the monoclinic crystal system and the C2/c (no. 15) space group. | |
dc.description.sponsorship | Egerton University, The University of KwaZulu-Natal | |
dc.identifier.citation | Mambanda, A., Kanyora, A. K., Ongoma, P., Gichumbi, J., & Omondi, R. O. (2022). Chlorido-(η 6-p-cymene)-(bis (pyrazol-1-yl) methane-κ 2 N, N′) Osmium (II) Tetrafluoroborate, C17H22BClF4N4Os. Molbank, 2022(3), M1429. | |
dc.identifier.uri | https://scholar.google.com/scholar?hl=en&as_sdt=0%2C5&q=Chlorido-%28%CE%B76-p-cymene%29-%28bis%28pyrazol-1-yl%29methane-+%CE%BA2N%2CNl%29Osmium%28II%29+Tetrafluoroborate%2C+C17H22BClF4N4Os&btnG= | |
dc.identifier.uri | https://repository.chuka.ac.ke/handle/123456789/16485 | |
dc.language.iso | en | |
dc.publisher | MDPI | |
dc.subject | arene osmium(II) complex | |
dc.subject | di(1H-pyrazol-1-yl)methane | |
dc.subject | para-cymene | |
dc.subject | piano stool geometry | |
dc.subject | pseudo-octahedral geometry | |
dc.title | Chlorido-(η6-p-cymene)-(bis(pyrazol-1-yl)methane- κ2N,Nl)Osmium(II) Tetrafluoroborate, C17H22BClF4N4Os | |
dc.type | Article |