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Synthesis and characterization of some new half-sandwich ruthenium(II) complexes with bidentate N,N′-ligands and their application in alcohol oxidation
(2016)
Graphical abstract
New ruthenium (II) pyridine-imine complexes have been prepared and characterized. They show good catalytic activity in the oxidation of alcohols to carbonyl products using NaIO4 in a H2O/tert-butanol mixture.
Crystal structure of η 6 -p-cymene-iodido-(N-isopropyl-1-(pyridin-2-yl) methanimine-κ 2N,N′)ruthenium(II) hexafluorophosphate(V), C19H26IN2F6Ru
(De Gruyter, 2019-12-07)
C19H26IN2F6Ru, triclinic, P¯1 (no. 2), a = 9.240(2) Å,
b = 10.019(3) Å, c = 12.689(3) Å, α = 78.921°, β = 81.596(10)°,
γ = 83.654°, V = 1136.30(5) Å3
, Z = 2, Rgt(F) = 0.0174,
wRref(F
2
) = 0.0440, T = 173 K.