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Application of arene ruthenium(II) complexes with pyridine-2-carboxaldimine ligands in the transfer hydrogenation of ketones
(Elsevier, 2016-05)
The reaction of various pyridine-2-carboxaldimine ligands with the [(η6-arene)Ru(μ-Cl)Cl]2 dimer followed by a metathesis reaction with ammonium hexaflourophosphate, yielded the ruthenium(II) arene complex salts ...
Synthesis and characterization of some new half-sandwich ruthenium(II) complexes with bidentate N,N′-ligands and their application in alcohol oxidation
(2016)
Graphical abstract
New ruthenium (II) pyridine-imine complexes have been prepared and characterized. They show good catalytic activity in the oxidation of alcohols to carbonyl products using NaIO4 in a H2O/tert-butanol mixture.
Crystal structure of chlorido-(η6 - toluene)(2,2′-bipyridine-κ2 N,N′)ruthenium(II) hexafluorophosphate, C17H16ClN2RuPF6
(De Gruyter, 2022)
C17H16ClN2RuPF6, monoclinic, P21/c (no. 14), a = 14.4426(9)
Å, b = 8.3311(5) Å, c = 16.413(1) Å, β = 109.2690°, V = 1864.2(2)
Å3
, Z = 4, Rgt(F) = 0.0309, wRref(F2
) = 0.0697, T = 173 K.
Crystal structure of η 6 -p-cymene-iodido-(N-isopropyl-1-(pyridin-2-yl) methanimine-κ 2N,N′)ruthenium(II) hexafluorophosphate(V), C19H26IN2F6Ru
(De Gruyter, 2019-12-07)
C19H26IN2F6Ru, triclinic, P¯1 (no. 2), a = 9.240(2) Å,
b = 10.019(3) Å, c = 12.689(3) Å, α = 78.921°, β = 81.596(10)°,
γ = 83.654°, V = 1136.30(5) Å3
, Z = 2, Rgt(F) = 0.0174,
wRref(F
2
) = 0.0440, T = 173 K.