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Synthesis and characterization of piano-stool ruthenium complexes with N,N′-pyridine imine bidentate ligands and their application in styrene oxidation
(Elsevier, 2016-04)
The new complexes [(η6-arene)RuCl(C5H4N-2-CH N-R)]PF6 (arene = C6H6 with R = 4- flourophenyl (1), 4-chlorophenyl (2), 4-bromophenyl (3), 4 -iodophenyl (4), 2, 5-dichlorophenyl (5) or p-cymene with R = 4-flourophenyl (6), ...
Application of arene ruthenium(II) complexes with pyridine-2-carboxaldimine ligands in the transfer hydrogenation of ketones
(Elsevier, 2016-05)
The reaction of various pyridine-2-carboxaldimine ligands with the [(η6-arene)Ru(μ-Cl)Cl]2 dimer followed by a metathesis reaction with ammonium hexaflourophosphate, yielded the ruthenium(II) arene complex salts ...
Antibacterial and antifungal activities of novel hydroxytriazenes
(2012-04-02)
In a search for new leads potent antimicrobial agents, an array of novel hydroxytriazenes i-xi were synthesized and characterized through their melting point, crystal shape, colour and elemental analysis. In vitro ...
Synthesis and characterization of some new half-sandwich ruthenium(II) complexes with bidentate N,N′-ligands and their application in alcohol oxidation
(2016)
Graphical abstract
New ruthenium (II) pyridine-imine complexes have been prepared and characterized. They show good catalytic activity in the oxidation of alcohols to carbonyl products using NaIO4 in a H2O/tert-butanol mixture.
Crystal structure of η 6 -p-cymene-iodido-(N-isopropyl-1-(pyridin-2-yl) methanimine-κ 2N,N′)ruthenium(II) hexafluorophosphate(V), C19H26IN2F6Ru
(De Gruyter, 2019-12-07)
C19H26IN2F6Ru, triclinic, P¯1 (no. 2), a = 9.240(2) Å,
b = 10.019(3) Å, c = 12.689(3) Å, α = 78.921°, β = 81.596(10)°,
γ = 83.654°, V = 1136.30(5) Å3
, Z = 2, Rgt(F) = 0.0174,
wRref(F
2
) = 0.0440, T = 173 K.
Polylactic acid (PLA) viscoelastic properties and their degradation compared with those of polyethylene
(Academic Journals, 2015-10-19)
Polyethylene (PE) films are widely used in packaging. PE is a thermoplastic manufactured from
nonrenewable petroleum resources. Due to its non–biodegradability, its films have posed serious
pollution problems e.g. visual ...