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Synthesis, characterization, and antimicrobial studies of half-sandwich η6-toluene ruthenium complexes with N,N′-bidentate ligands
(Taylor and Francis, 2020-07-29)
Nine new complexes [(η6-C6H5-CH3)RuLCl]+(PF6)ˉ (where L = N,N′-bidentate ligand; (C5H4NCH = N-Ar) where Ar = 4-methylphenyl (C20H20ClF6N2PRu, 1); 3,4-dimethylphenyl (C21H22ClF6N2PRu, 2); 2,4,6-trimethylphenyl (C21H24ClF6N2PRu, ...
Crystal structure of chlorido-(η6 - toluene)(2,2′-bipyridine-κ2 N,N′)ruthenium(II) hexafluorophosphate, C17H16ClN2RuPF6
(De Gruyter, 2022)
C17H16ClN2RuPF6, monoclinic, P21/c (no. 14), a = 14.4426(9)
Å, b = 8.3311(5) Å, c = 16.413(1) Å, β = 109.2690°, V = 1864.2(2)
Å3
, Z = 4, Rgt(F) = 0.0309, wRref(F2
) = 0.0697, T = 173 K.