Search
Now showing items 1-4 of 4
Synthesis and characterization of half-sandwich ruthenium(II) complexes with N-alkyl pyridyl-imine ligands and their application in transfer hydrogenation of ketones
(2016-08-24)
A series of new arene ruthenium(II) complexes were prepared by reaction of ruthenium(II) precursors of the general formula [(η6-arene)Ru(μ-Cl)Cl]2 with N,N′-bidentate pyridyl-imine ligands to form complexes of the type ...
Synthesis and characterization of piano-stool ruthenium complexes with N,N′-pyridine imine bidentate ligands and their application in styrene oxidation
(Elsevier, 2016-04)
The new complexes [(η6-arene)RuCl(C5H4N-2-CH N-R)]PF6 (arene = C6H6 with R = 4- flourophenyl (1), 4-chlorophenyl (2), 4-bromophenyl (3), 4 -iodophenyl (4), 2, 5-dichlorophenyl (5) or p-cymene with R = 4-flourophenyl (6), ...
Application of arene ruthenium(II) complexes with pyridine-2-carboxaldimine ligands in the transfer hydrogenation of ketones
(Elsevier, 2016-05)
The reaction of various pyridine-2-carboxaldimine ligands with the [(η6-arene)Ru(μ-Cl)Cl]2 dimer followed by a metathesis reaction with ammonium hexaflourophosphate, yielded the ruthenium(II) arene complex salts ...
Synthesis and characterization of some new half-sandwich ruthenium(II) complexes with bidentate N,N′-ligands and their application in alcohol oxidation
(2016)
Graphical abstract
New ruthenium (II) pyridine-imine complexes have been prepared and characterized. They show good catalytic activity in the oxidation of alcohols to carbonyl products using NaIO4 in a H2O/tert-butanol mixture.