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A study of new half-sandwich Osmium(II) complexes with bidentate N,N-chelating ligands and their use in the transfer hydrogenation of ketones
(2016-11)
The reaction of appropriate N,N-bidentate ligands with the [(η6-p-cymene)Os(μ-Cl)Cl]2 dimer, followed by metathesis reaction with NH4PF6, gave the new osmium(II) arene complex salts [(η6-p-cymene)OsCl(C5H4N-2-CH=N-R]PF6, ...