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Crystal structure of η6-p-cymene-iodido- (N-isopropyl-1-(pyridin-2-yl) methanimine-κ2N, N′) ruthenium (II) hexafluorophosphate (V), C19H26IN2F6Ru
(2019-12-07)
C19H26IN2F6Ru, triclinic, P1̄ (no. 2), a = 9.240(2) Å, b = 10.019(3) Å, c = 12.689(3) Å, α = 78.921°, β = 81.596(10)°, γ = 83.654°, V = 1136.30(5) Å3, Z = 2, Rgt(F) = 0.0174, wRref(F2) = 0.0440, T = 173 K.
Synthesis and characterization of water-soluble arene- ruthenium complexes and their application in biphasic olefin oxidation
(2018-12-25)
New water-soluble complexes [(η6-C6H6)RuCl(C5H4N-2-CH = N-R)]Cl (1) (with R = 4-hydroxymethylphenyl (a), 2,4-dichlorophenyl (b), 2-fluorophenyl (c), 3-carboxyphenyl (d)) have been synthesized by reacting [(η6-C6H6)Ru(μ-Cl)Cl]2 ...
Crystal structure of chlorido-(η5-pentamethylcyclopenta dienyl)-((bis-pyrazol-1-yl) methane-κ2N, N′) rhodium (III) hexafluorophosphate
(2019-11-13)
C17H23ClN4RhF6P, monoclinic, P21/c (no. 14), a = 10.6954(2) Å, b = 15.3868(3) Å, c = 12.6130(2) Å, β = 90.5590(10)°, V = 2075.60(7) Å3, Z = 4, Rgt(F) = 0.0296, wRref(F2) = 0.0727, T = 100(2) K.
Crystal structure of chlorido-(η6-p-cymene)-(N- (2-fluorophenyl)-1-(pyridin-2-yl) methanimine-κ2N, N′) ruthenium (II)–acetone (1/1), C22H23ClN2F7OPRu.
(2010-01)
C 22 H 23 ClN 2 F 7 OPRu, monoclinic, P 2 1 / c (no. 14), a = 7.30480(10) Å, b = 12.9540(3) Å, c = 28.7076(6) Å, β = 96.6990(10)°, V = 2697.95(9) Å ³ , Z = 4, Rgt ( F ) = 0.0196, wRref ( F² ) = 0.0479, T = 100(2) K.
Synthesis and characterization of half-sandwich ruthenium(II) complexes with N-alkyl pyridyl-imine ligands and their application in transfer hydrogenation of ketones
(2016-08-24)
A series of new arene ruthenium(II) complexes were prepared by reaction of ruthenium(II) precursors of the general formula [(η6-arene)Ru(μ-Cl)Cl]2 with N,N′-bidentate pyridyl-imine ligands to form complexes of the type ...
Synthesis and characterization of piano-stool ruthenium complexes with N,N′-pyridine imine bidentate ligands and their application in styrene oxidation
(Elsevier, 2016-04)
The new complexes [(η6-arene)RuCl(C5H4N-2-CH N-R)]PF6 (arene = C6H6 with R = 4- flourophenyl (1), 4-chlorophenyl (2), 4-bromophenyl (3), 4 -iodophenyl (4), 2, 5-dichlorophenyl (5) or p-cymene with R = 4-flourophenyl (6), ...
Application of arene ruthenium(II) complexes with pyridine-2-carboxaldimine ligands in the transfer hydrogenation of ketones
(Elsevier, 2016-05)
The reaction of various pyridine-2-carboxaldimine ligands with the [(η6-arene)Ru(μ-Cl)Cl]2 dimer followed by a metathesis reaction with ammonium hexaflourophosphate, yielded the ruthenium(II) arene complex salts ...
Synthesis and characterization of some new half-sandwich ruthenium(II) complexes with bidentate N,N′-ligands and their application in alcohol oxidation
(2016)
Graphical abstract
New ruthenium (II) pyridine-imine complexes have been prepared and characterized. They show good catalytic activity in the oxidation of alcohols to carbonyl products using NaIO4 in a H2O/tert-butanol mixture.
Crystal structure of η 6 -p-cymene-iodido-(N-isopropyl-1-(pyridin-2-yl) methanimine-κ 2N,N′)ruthenium(II) hexafluorophosphate(V), C19H26IN2F6Ru
(De Gruyter, 2019-12-07)
C19H26IN2F6Ru, triclinic, P¯1 (no. 2), a = 9.240(2) Å,
b = 10.019(3) Å, c = 12.689(3) Å, α = 78.921°, β = 81.596(10)°,
γ = 83.654°, V = 1136.30(5) Å3
, Z = 2, Rgt(F) = 0.0174,
wRref(F
2
) = 0.0440, T = 173 K.